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Trifluoromethanesulfonic acid

CAS Number
1493-13-6
EC Number
216-087-5
Chemical Formula
CHF3O3S
Molecular Weight
150.08 g/mol

Description

Trifluoromethanesulfonic acid (CAS 1493-13-6 ), commercially known as triflic acid or TfOH, is one of the strongest known Brønsted acids and a highly reactive proton donor. Its primary industrial role is as a superacid catalyst and reagent in demanding synthetic and manufacturing processes where conventional acids lack sufficient reactivity. In pharmaceutical synthesis, TfOH drives acid-catalyzed cyclizations, glycosylations, and Friedel-Crafts-type reactions where milder acids fail to achieve acceptable yields or selectivity. Polymer manufacturers use it to initiate cationic polymerization and produce high-performance specialty polymers, including certain polybenzimidazoles and polyarylenes used in membrane applications. In textile and paper processing, it functions as a catalyst for surface treatment and finishing chemistries requiring precise pH control under aggressive conditions. Triflate salts derived from TfOH also serve as precursors to ionic liquid systems and metal triflate Lewis acid catalysts used across fine chemical Contact us for supply of Trifluoromethanesulfonic acid Request Quote

Other Names (Synonyms)

Triflic acid | TfOH

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point<25 °C
Boiling Point162 °C
Density1.69 g/cm³ (liquid)
Flash PointNone
AppearanceClear very light yellow liquid
Colorslightly brown
FormFuming Liquid
Water SolubilitySOLUBLE
Vapor Pressure8 mm Hg ( 25 °C)
Refractive Indexn 20/D 1.327(lit.)
pH<1 (H2O)
Log P0.3 at 25℃

Safety & Handling

Danger
GHS05· CorrosiveGHS07· Irritant

Hazard Statements

H290May be corrosive to metals
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H319Causes serious eye irritation
H335May cause respiratory irritation

Precautionary Statements

P234Keep only in original packaging.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P316Get emergency medical help immediately.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P363Wash contaminated clothing before reuse.
P390Absorb spillage to prevent material damage.
P405Store locked up.
P406Store in a corrosion-resistant/… container with a resistant inner liner.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P317Get emergency medical help.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P233Store in a well-ventilated place. Keep container tightly closed.
P331Rinse mouth. Do NOT induce vomiting.
P354IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29049020
UN Number3265
ADR Class8
Packing GroupII
Storage Class8A - Combustible corrosive hazardous materials
WGK (Germany)2