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tert-butyl peroxybenzoate

CAS Number
614-45-9
EC Number
210-382-2
Chemical Formula
C11H14O3
Molecular Weight
194.23 g/mol

Description

Tert-butyl peroxybenzoate (CAS 614-45-9 ), commonly sourced under the abbreviation TBPB or as tert-butyl perbenzoate, is an organic peroxide used as a free-radical initiator and curing agent across polymer and coatings manufacturing. Its controlled decomposition temperature makes it a practical choice for medium-temperature cure systems where processing window and final product performance must be balanced. In rubber and tire production, TBPB initiates cross-linking of elastomers. This process improves mechanical strength and heat resistance in finished compounds. Unsaturated polyester resins and gel coats in composites manufacturing rely on TBPB as a cure initiator, particularly where surface quality and cure speed are critical. Coatings formulators use it to drive radical polymerization in acrylic and styrenic systems, enabling consistent film formation at elevated cure temperatures. In plastics processing, it functions as a peroxide crosslinker for polyethylene. It also serves as a grafting initiator for modifying polymer backbones. TBPB is supplied as a clear to pale yellow liquid, typically at concentrations of 98% pure or as diluted formulations for safer handling in industrial settings. It is available in technical grade , with supply packaged to meet peroxide transport and storage regulations. Drum and IBC quantities are standard for industrial buyers seeking reliable chemical performance. Contact us for supply of tert-butyl peroxybenzoate Request Quote

Other Names (Synonyms)

TBPB | tert-Butyl perbenzoate | Chaloxyd tbpb | Perbutyl Z | Esperox 10 | t-Butyl perbenzoate | Trigonox C | Benzoyl tert-butyl peroxide

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point8 °C
Boiling Point75-76 °C @ Press: 0.2 Torr
Density1.021 g/cm³ @ Temp: 25 °C
Flash Point200 °F
Appearancecolourless or slightly yellow liquid
ColorClear yellow
Odormild aromatic odor
FormLiquid
Water SolubilityImmiscible
Vapor Pressure3.36 mm Hg ( 50 °C)
Refractive Indexn 20/D 1.499(lit.)
Log P3 at 25℃

Safety & Handling

Danger
GHS02· FlammableGHS07· IrritantGHS09· EnvironmentGHS08· Health Hazard

Hazard Statements

H227Combustible liquid
H242Heating may cause a fire
H315Causes skin irritation
H317May cause an allergic skin reaction
H320Causes eye irritation
H332Harmful if inhaled
H371May cause damage to organs
H400Very toxic to aquatic life
H410Very toxic to aquatic life with long lasting effects
H412Harmful to aquatic life with long lasting effects

Precautionary Statements

P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P234Keep only in original packaging.
P235Keep cool.
P240Ground and bond container and receiving equipment.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P317Get emergency medical help.
P321Specific treatment (see … on this label).
P391Collect spillage.
P403Store in a well-ventilated place.
P405Store locked up.
P410Protect from sunlight.
P411Store at temperatures not exceeding … °C/…°F.
P420Store away from other materials.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P317Get emergency medical help.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P364Take off contaminated clothing and wash it before reuse.
P378Use … for extinction.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29163900
UN Number3103
ADR Class5.2
Storage Class4.1A - Other explosive hazardous materials
WGK (Germany)2