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di-tert-butyl peroxide

CAS Number
110-05-4
EC Number
203-733-6
Chemical Formula
C8H18O2
Molecular Weight
146.23 g/mol

Description

Di-tert-butyl peroxide (CAS 110-05-4 ), commonly known as DTBP, is an organic peroxide used as a high-temperature free-radical initiator and cross-linking agent across rubber and polymer manufacturing. Its relatively high decomposition temperature makes it the preferred choice where lower-temperature peroxides would activate prematurely during compounding or processing. In rubber and tire production, DTBP initiates cross-linking. It is used for EPDM, silicone, and natural rubber compounds, delivering vulcanizates with improved heat resistance compared to sulfur-cured alternatives. Polyethylene and polypropylene producers use it to initiate reactions. These reactions include controlled degradation or grafting, modifying melt flow and mechanical properties for film, pipe, and wire insulation grades. It also functions as a polymerization initiator for styrenic and acrylic monomers. A high-temperature kick-off point is required to match reactor conditions. In the production of unsaturated polyester resins, DTBP enables elevated-temperature cure cycles that reduce cycle times in compression molding. Di-tert-butyl peroxide is supplied as a clear liquid, typically at concentrations of 98% or higher for industrial use. It is also available in diluted or blended formulations on inert carriers for transport. Technical grade is the standard commercial specification, with product conforming to relevant peroxide handling classifications for storage and logistics. This ensures safety and stability during the supply chain process. Contact us for supply of di-tert-butyl peroxide Request Quote

Other Names (Synonyms)

DTBP | tert-Butyl peroxide | t-Butyl peroxide | Trigonox B | Cadox TBP | Cadox | Kayabutyl D | Perbutyl D

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point-40 °C
Boiling Point111 °C
Density0.7910 g/cm³ @ Temp: 25 °C
Flash Point34 °F
Appearancecolourless liquid
ColorClear
Odordistinctive odor
FormLiquid
Water Solubilityimmiscible
Vapor Pressure40 mm Hg ( 20 °C)
Refractive Indexn 20/D 1.3891(lit.)
Log P3.2 at 22℃

Safety & Handling

Danger
GHS02· FlammableGHS08· Health HazardGHS07· Irritant

Hazard Statements

H225Highly Flammable liquid and vapor
H242Heating may cause a fire
H319Causes serious eye irritation
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H341Suspected of causing genetic defects
H402Harmful to aquatic life
H412Harmful to aquatic life with long lasting effects

Precautionary Statements

P203Obtain, consult and follow expert instructions for use.
P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233Keep container tightly closed.
P234Keep only in original packaging.
P235Keep cool.
P240Ground and bond container and receiving equipment.
P241Use explosion-proof equipment.
P242Use non-sparking tools.
P243Take action to prevent static discharges.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P284In case of inadequate ventilation wear respiratory protection.
P318IF exposed or concerned, get medical advice.
P403Store in a well-ventilated place.
P405Store locked up.
P410Protect from sunlight.
P411Store at temperatures not exceeding … °C/…°F.
P420Store away from other materials.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P316Get emergency medical help immediately.
P378Use … for extinction.
P235Store in a well-ventilated place. Keep cool.
P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29096000
UN Number3107
ADR Class5.2
Storage Class5.2 - Organic peroxides and self-reacting hazardous materials
WGK (Germany)1