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1-bromo-4-iodobenzene

CAS Number
589-87-7
EC Number
209-662-7
Chemical Formula
C6H4BrI
Molecular Weight
282.90 g/mol

Description

1-Bromo-4-iodobenzene (CAS 589-87-7 ), also known as p-bromoiodobenzene, is a dual-halogenated aromatic building block used across pharmaceutical synthesis and specialty chemical manufacturing. The presence of two distinct halogen substituents on the benzene ring allows selective cross-coupling reactions, making it a practical starting material for constructing complex molecular architectures. In pharmaceutical intermediate synthesis, it serves as a key precursor in palladium-catalyzed reactions where chemists exploit the differential reactivity of bromine and iodine to achieve regioselective functionalization. Polymer and materials chemists use it to introduce halogenated aryl units into flame-retardant polymer systems, particularly where controlled halogen loading is required for specific industrial applications. In dye and pigment manufacturing, it functions as a reactive intermediate for producing brominated and iodinated aromatic colorants used in various textile and leather applications across the globe. It also supports the development of specialty monomers and cross-linkers in advanced polymer formulations targeting specific thermal or electronic performance profiles for high-tech manufacturing sectors. 1-Bromo-4-iodobenzene is supplied as a white to off-white crystalline solid. It is available in technical and high-purity grades, with purity levels typically ranging from 98% to 99%+ for fine chemical synthesis. Packaging options generally range from small laboratory quantities up to multi-kilogram lots for industrial procurement, ensuring reliable supply chains for both research and large-scale production needs. Contact us for supply of 1-bromo-4-iodobenzene Request Quote

Other Names (Synonyms)

p-Bromoiodobenzene | Benzene, 1-bromo-4-iodo- | 4-bromo-1-iodobenzene | 4-iodobromobenzene | 4-bromophenyl iodide | 4-iodo-1-bromobenzene | R9LDG2XS7C

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point92 °C
Boiling Point90 °C
Density2.2236 (rough estimate)
Flash Point120-122°C/14mm
Appearancewhite to brown cryst. powder, crystals or needles
ColorWhite to brown
FormCrystalline Powder, Crystals or Needles
Water SolubilityInsoluble in water.
Refractive Index1.6618 (estimate)

Safety & Handling

Warning
GHS07· Irritant

Hazard Statements

H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
H413May cause long lasting harmful effects to aquatic life

Precautionary Statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P317Get emergency medical help.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P364Take off contaminated clothing and wash it before reuse.
P233Store in a well-ventilated place. Keep container tightly closed.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29036990
Storage Class11 - Combustible Solids
WGK (Germany)3