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Ammonium bifluoride

CAS Number
1341-49-7
EC Number
215-676-4
Chemical Formula
F2H.H4N
Molecular Weight
57.044 g/mol

Description

Ammonium bifluoride (CAS 1341-49-7 ), also known as ABF, is an inorganic fluoride salt used across metal treatment, surface preparation, and industrial cleaning processes. It delivers controlled fluoride activity in acidic conditions, making it a practical alternative to hydrofluoric acid in applications where handling pure HF is operationally difficult. In metal processing and mining, ABF functions as a flux and etchant for removing oxide layers from aluminum, stainless steel, and other alloys prior to finishing or refining. Electronics manufacturers use it in glass and silicon etching, where precise surface modification is required for component fabrication during the manufacturing process. In textile and paper production, it acts as a pH buffer and flame retardant additive, contributing to fire-resistance treatments in various types of finished goods. Building and construction applications include masonry cleaning and concrete surface treatment, where its fluoride content dissolves silicates and mineral deposits effectively. Ammonium bifluoride is supplied as white crystalline granules or powder. Technical grade is the standard commercial form, with purity levels typically at 95–98%+. Bulk packaging in fiber drums or HDPE containers is common for industrial supply, with smaller quantities available for laboratory or specialty use in research settings. Contact us for supply of Ammonium bifluoride Request Quote

Other Names (Synonyms)

Ammonium difluoride | Ammonium hydrogen difluoride | Ammonium hydrofluoride | Acid ammonium fluoride | Ammonium acid fluoride | Ammonium hydrogen bifluoride | Ammonium fluoride ((NH4)(HF2)) | Fluorure acide d'ammonium | ABF

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point125.6 °C
Boiling Point240 °C (decomp)
Density1.50 g/cm³
Flash Point238°C
Appearancewhite scales or flakes
ColorWhite
Odoracidic odor
FormSolid
Water Solubility630 g/L (20 ºC)
Vapor Pressure1 hPa (20 °C)
pH2 (5.7g/l, H2O, 20℃)

Safety & Handling

Danger
GHS05· CorrosiveGHS06· ToxicGHS07· IrritantGHS08· Health Hazard

Hazard Statements

H301Toxic if swallowed
H310Fatal in contact with skin
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H331Toxic if inhaled
H335May cause respiratory irritation
H370Causes damage to organs
H371May cause damage to organs
H372Causes damage to organs through prolonged or repeated exposure
H373May causes damage to organs through prolonged or repeated exposure

Precautionary Statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P262Do not get in eyes, on skin, or on clothing.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P363Wash contaminated clothing before reuse.
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P316Get emergency medical help immediately.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316Get emergency medical help immediately.
P364Take off immediately all contaminated clothing and wash it before reuse.
P233Store in a well-ventilated place. Keep container tightly closed.
P331Rinse mouth. Do NOT induce vomiting.
P354IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code28261900
UN Number1727
ADR Class8
Packing GroupII
WGK (Germany)1