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Trimellitic anhydride

CAS Number
552-30-7
EC Number
209-008-0
Chemical Formula
C9H4O5
Molecular Weight
192.12 g/mol

Description

Trimellitic anhydride (CAS 552-30-7 ), commonly abbreviated as TMA, is a reactive aromatic anhydride used as a monomer and curing agent across polymer and coating systems. It introduces carboxylic acid functionality into resin backbones, enabling cross-linking, chain extension, and surface-reactive formulations. In high-performance coatings, TMA is reacted with polyols or amines to produce polyimide and polyester resins that withstand elevated temperatures and chemical exposure. These specialized resins are essential for industrial applications requiring durability. The plastics industry uses it to manufacture plasticizers, particularly trimellitate esters, for flexible PVC in wire and cable insulation. These materials require low volatility at high operating temperatures to ensure safety and longevity. Adhesive and sealant formulators incorporate TMA as a cross-linking monomer to improve heat resistance and adhesion to metal substrates. This chemical property makes it a vital component in demanding structural bonding applications. In pigment and dye manufacturing, it acts as an intermediate in the synthesis of reactive dyes and color developers. Its unique structure allows for the creation of stable and vibrant colorants used in various industrial sectors. Trimellitic anhydride is supplied as an off-white to pale yellow crystalline powder or flake. Technical grade is the standard commercial form, with purity typically at 98–99%+ by GC, ensuring consistent performance in chemical synthesis. Packaging ranges from multi-wall bags to bulk supersacks to meet diverse logistical needs. Storage requirements for moisture-sensitive handling are strictly communicated in product documentation to maintain material integrity. Contact us for supply of Trimellitic anhydride Request Quote

Other Names (Synonyms)

Trimellitic acid cyclic 1,2-anhydride | Trimellitic acid anhydride | Trimellitic acid 1,2-anhydride | Trimellic acid anhydride | Trimellic acid 1,2-anhydride | Benzene-1,2,4-tricarboxylic-1,2-anhydride | Anhydrotrimellitic acid | Anhydrotrimellic acid | TMA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point161-163.5 °C
Boiling Point390 °C
Density1.54
Flash Point227 °C
AppearanceTrimellitic anhydride is a crystalline solid. It is the anhydride of trimellitic acid (1,2,4-benzenetricarboxylic acid).
ColorWhite to off-white
FormFlakes
Water SolubilityDECOMPOSES
Vapor Pressure<0.01 mm Hg ( 20 °C)
Refractive Index1.4717 (estimate)
pH2 (21g/l, H2O, 20℃)
Log P0.06-0.54 at 20℃

Safety & Handling

Danger
GHS05· CorrosiveGHS07· IrritantGHS08· Health Hazard

Hazard Statements

H303May be harmful if swallowed
H316Causes mild skin irritation
H317May cause an allergic skin reaction
H318Causes serious eye damage
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335May cause respiratory irritation
H370Causes damage to organs
H372Causes damage to organs through prolonged or repeated exposure

Precautionary Statements

P233Keep container tightly closed.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P272Contaminated work clothing should not be allowed out of the workplace.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P284In case of inadequate ventilation wear respiratory protection.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P403Store in a well-ventilated place.
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P317Get emergency medical help.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P317Get emergency medical help.
P316Get emergency medical help immediately.
P364Take off contaminated clothing and wash it before reuse.
P233Store in a well-ventilated place. Keep container tightly closed.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29173980
Storage Class11 - Combustible Solids
WGK (Germany)1