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Pentamethyldiethylenetriamine

CAS Number
3030-47-5
EC Number
221-201-1
Chemical Formula
C9H23N3
Molecular Weight
173.30 g/mol

Description

Pentamethyldiethylenetriamine (CAS 3030-47-5 ), commonly abbreviated as PMDETA, is a tertiary triamine used primarily as a ligand and catalyst in controlled radical polymerization and polyurethane systems. Its ability to coordinate with metal centers makes it a key enabler in atom transfer radical polymerization (ATRP) processes and amine-catalyzed cure reactions in various industrial sectors. In polymer manufacturing, PMDETA functions as a ligand for copper catalysts in ATRP, enabling precise molecular weight control in the production of specialty acrylates, methacrylates, and block copolymers. Polyurethane formulators use it as a tertiary amine catalyst to balance gel and blow reactions in flexible and rigid foam systems, as well as in coatings and adhesives for construction. In epoxy and sealant formulations, it accelerates cure at ambient or elevated temperatures, supporting faster line speeds in industrial bonding applications and high-performance manufacturing environments. Water treatment chemical producers also employ it as a building block in the synthesis of chelating agents and corrosion inhibitors, expanding its utility beyond traditional polymer science. PMDETA is supplied as a liquid at standard commercial purity levels, typically 98% or higher. Technical grade is the predominant specification available in the market, supplied in drums or IBCs. It is not commonly offered in food or pharmaceutical grades, and sourcing is primarily directed toward industrial and research applications requiring high-performance chemical intermediates. Contact us for supply of Pentamethyldiethylenetriamine Request Quote

Other Names (Synonyms)

PMDT | pmdien | N,N',N''-pentamethyldiethylenetriamine | N,N,N',N'',N''-pentamethyldiethylenetriamine | N-(2-(dimethylamino)ethyl)-N,N',N'-trimethyl-1,2-ethanediamine | bis(2-dimethylaminoethyl)(methyl)amine | 2,5,8-trimethyl-2,5,8-triazanonane | 2,2'-(methylazanediyl)bis(N,N-dimethylethanamine) | PMDETA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point162-163 °C
Boiling Point198 °C
Density0.83 g/mL at 25 °C(lit.)
Flash Point128 °F
Appearancecolourless liquid with an amine odour
ColorWhite
OdorFishy, ammoniacal odor
FormPowder
Water SolubilityMiscible in water.
Vapor Pressure0.23 mm Hg ( 20 °C)
Refractive Indexn 20/D 1.442(lit.)
pH11.9 (100g/l, H2O, 20℃)
Log P-2.1 at 25℃

Safety & Handling

Danger
GHS05· CorrosiveGHS06· ToxicGHS07· IrritantGHS02· FlammableGHS08· Health Hazard

Hazard Statements

H226Flammable liquid and vapor
H302Harmful if swallowed
H311Toxic in contact with skin
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H331Toxic if inhaled
H332Harmful if inhaled
H335May cause respiratory irritation
H373May causes damage to organs through prolonged or repeated exposure
H402Harmful to aquatic life
H412Harmful to aquatic life with long lasting effects H311+
H331Toxic in contact with skin or if inhaled.

Precautionary Statements

P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233Keep container tightly closed.
P240Ground and bond container and receiving equipment.
P241Use explosion-proof equipment.
P242Use non-sparking tools.
P243Take action to prevent static discharges.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P262Do not get in eyes, on skin, or on clothing.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P363Wash contaminated clothing before reuse.
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P317Get emergency medical help.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P364Take off immediately all contaminated clothing and wash it before reuse.
P378Use … for extinction.
P233Store in a well-ventilated place. Keep container tightly closed.
P235Store in a well-ventilated place. Keep cool.
P331Rinse mouth. Do NOT induce vomiting.
P354IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29212900
UN Number2734
ADR Class8
Packing GroupII
WGK (Germany)2