HomeProducts

4-bromo-1,8-naphthalic anhydride

CAS Number
81-86-7
EC Number
201-382-3
Chemical Formula
C12H5BrO3
Molecular Weight
277.07 g/mol

Description

4-Bromo-1,8-naphthalic anhydride (CAS 81-86-7 ) is a halogenated cyclic anhydride used as a reactive intermediate in the synthesis of naphthalimide-based dyes, fluorescent pigments, and specialty polymers. Its bromine substituent provides a versatile handle for further functionalization, making it a key building block in dye chemistry and materials science for various industrial applications. In textile and printing applications, it serves as a precursor to high-performance fluorescent dyes used in fabric brightening and inkjet colorants. Polymer chemists incorporate it into polyimide backbones. These high-temperature polymer backbones are utilized where controlled optical or electronic properties are required. The compound is also used in pharmaceutical intermediate synthesis for bioactive candidates. The naphthalimide scaffold is elaborated through palladium-catalyzed cross-coupling or nucleophilic substitution at the bromine site. In specialty pigment manufacturing, it contributes to the production of vat dyes. It is also used for solvent dyes for plastics coloration and packaging inks. 4-Bromo-1,8-naphthalic anhydride is supplied as a solid powder, typically in off-white to pale yellow form. It is available in technical and high-purity research grades, with purity specifications commonly ranging from 97% to 99%+ depending on the intended application and specific requirements. Packaging options range from small laboratory quantities to multi-kilogram industrial lots. This ensures flexibility for both research development and large-scale commercial manufacturing processes. Contact us for supply of 4-bromo-1,8-naphthalic anhydride Request Quote

Other Names (Synonyms)

6-Bromo-1H,3H-naphtho[1,8-cd]pyran-1,3-dione | 1H,3H-Naphtho[1,8-cd]pyran-1,3-dione, 6-bromo- | RefChem:437750 | Naphthalic anhydride, 4-bromo- | 4-Bromonaphthalic anhydride | 4-Bromo-1,8-naphthalenedicarboxylic anhydride

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point218-220 °C
Boiling Point467.2±28.0 °C(Predicted)
Density1.812±0.06 g/cm3(Predicted)
ColorOff-White to Pale Yellow
FormSolid

Safety & Handling

Warning
GHS07· Irritant

Hazard Statements

H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation

Precautionary Statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P317Get emergency medical help.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P364Take off contaminated clothing and wash it before reuse.
P233Store in a well-ventilated place. Keep container tightly closed.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29173990
Storage Class11 - Combustible Solids
WGK (Germany)3