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2,5-dimethyl-2,5-di(tert-butylperoxy)hexane

CAS Number
78-63-7
EC Number
201-128-1
Chemical Formula
C16H34O4
Molecular Weight
290.44 g/mol

Description

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane , identified by CAS 78-63-7 , is a high-temperature organic peroxide used as a free-radical initiator and cross-linking agent in polymer processing. Its thermal stability at moderate storage temperatures makes it a preferred choice where controlled decomposition at elevated cure temperatures is required for industrial applications. In rubber compounding, it cross-links EPDM, silicone, and natural rubber to improve heat resistance and compression set performance in seals, gaskets, and automotive components. Polyolefin producers use it to initiate cross-linking in PE and PP, producing materials suited for wire and cable insulation, pipes, and high-performance foam products. It also functions as a polymerization initiator in the production of specialty resins and thermoplastic elastomers where precise molecular weight control is needed for manufacturing. In the tire industry, it supports sulfur-free cure systems where low extractables and improved aging properties are critical for long-term durability and performance standards. Supplied as a liquid or absorbed onto an inert carrier as a diluted paste or powder blend, standard commercial concentrations include 90% active content liquid and diluted grades. The Technical grade is the primary market specification, with purity and active oxygen content confirmed by certificate of analysis for every batch produced. Contact us for supply of 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane Request Quote

Other Names (Synonyms)

Varox | Perhexa 3M40 | Trigonox 101-101/45 | Peroxide, 1,1′-(1,1,4,4-tetramethyl-1,4-butanediyl)bis[2-(1,1-dimethylethyl) | Peroxide, (1,1,4,4-tetramethyltetramethylene)bis[tert-butyl | Peroxide, (1,1,4,4-tetramethyl-1,4-butanediyl)bis[(1,1-dimethylethyl)

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point80 °C
Boiling Point42 °C @ Press: 0.06 Torr
Density0.8728 g/cm³ @ Temp: 28 °C
Flash Point149 °F
Appearancecolourless to light yellow liquid
ColorColourless
FormOil
Water Solubilityimmiscible
Vapor Pressure0.002Pa at 20℃
Refractive Indexn 20/D 1.423(lit.)
Log P7.34 at 20℃

Safety & Handling

Danger
GHS02· FlammableGHS07· Irritant

Hazard Statements

H226Flammable liquid and vapor
H227Combustible liquid
H242Heating may cause a fire
H315Causes skin irritation
H319Causes serious eye irritation
H413May cause long lasting harmful effects to aquatic life

Precautionary Statements

P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233Keep container tightly closed.
P234Keep only in original packaging.
P235Keep cool.
P240Ground and bond container and receiving equipment.
P241Use explosion-proof equipment.
P242Use non-sparking tools.
P243Take action to prevent static discharges.
P264Wash … thoroughly after handling.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P321Specific treatment (see … on this label).
P403Store in a well-ventilated place.
P410Protect from sunlight.
P411Store at temperatures not exceeding … °C/…°F.
P420Store away from other materials.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P352IF ON SKIN: Wash with plenty of water.
P317Get emergency medical help.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P364Take off contaminated clothing and wash it before reuse.
P378Use … for extinction.
P235Store in a well-ventilated place. Keep cool.
P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29012990
UN Number3108
ADR Class5.2
WGK (Germany)1