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Sodium bisulfite

CAS Number
7631-90-5
EC Number
231-548-0
Chemical Formula
H2O3S.Na
Molecular Weight
104.06 g/mol

Description

Sodium bisulfite (CAS 7631-90-5 ), also sold as sodium bisulphite and designated E222 in food applications, is an inorganic sulfite salt used commercially as a reducing agent, preservative, and oxygen scavenger across multiple industries. SBS delivers reliable antioxidant and antimicrobial action at relatively low use concentrations, making it a cost-effective functional ingredient for formulators and process engineers in various sectors. In food and beverage production, E222 prevents oxidative browning and microbial spoilage in fruit products, wines, dried foods, and seafood processing. Water treatment operations rely on sodium bisulfite to dechlorinate potable water. It is used for treating boiler feedwater, neutralizing residual chlorine before downstream processing or discharge. Textile and paper manufacturers apply it as a bleaching and reducing agent for pulp brightening and dye stripping. In pharmaceutical manufacturing, it functions as an antioxidant stabilizer in injectable formulations and oral liquid preparations where oxygen-sensitive active ingredients require protection from degradation. Sodium bisulfite is supplied as a white to off-white crystalline powder or granules, with liquid solution forms also available for industrial water treatment applications. Standard commercial grades include food-grade material. These grades are FCC and E222-compliant, with purity levels typically ranging from 58% to 65% active SO₂ equivalent. Pharmaceutical-grade material meeting USP or Ph.Eur. specifications is also available. These high-purity options are specifically designed for regulated manufacturing environments. The material remains a versatile chemical essential for maintaining product stability and process efficiency globally. Contact us for supply of Sodium bisulfite Request Quote

Other Names (Synonyms)

sodium hydrogensulfite | sodium bisulphite | sodium acid bisulfite | saures Natriumsulfit | primäres Natriumsulfit | monosodium salt of sulfurous acid | Bisulfite de sodium | Monosodium sulfite | SBS | E222

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point150 °C
Density1.48 g/cm³
AppearanceSodium bisulfite is a white crystalline solid. Slight odor of sulfur dioxide and a disagreeable taste. Slowly oxidized to the sulfate on exposure to air
ColorWhite
OdorSlight odor of sulfur dioxide
FormPowder/Solid
Water Solubility300 g/L
Vapor Pressure40 hPa ( 20 °C)
pH4.5 (20°C in H2O)

Safety & Handling

Warning
GHS07· IrritantGHS08· Health HazardGHS05· Corrosive

Hazard Statements

H302Harmful if swallowed
H317May cause an allergic skin reaction
H318Causes serious eye damage
H320Causes eye irritation
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335May cause respiratory irritation
H372Causes damage to organs through prolonged or repeated exposure

Precautionary Statements

P233Keep container tightly closed.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P272Contaminated work clothing should not be allowed out of the workplace.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P284In case of inadequate ventilation wear respiratory protection.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P403Store in a well-ventilated place.
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P317Get emergency medical help.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P317Get emergency medical help.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P316Get emergency medical help immediately.
P364Take off contaminated clothing and wash it before reuse.
P233Store in a well-ventilated place. Keep container tightly closed.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code28323010
UN Number2693
Storage Class13 - Non Combustible Solids
WGK (Germany)1