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1,4-Butanediol dimethacrylate

CAS Number
2082-81-7
EC Number
218-218-1
Chemical Formula
C12H18O4
Molecular Weight
226.27 g/mol

Description

1,4-Butanediol dimethacrylate (CAS 2082-81-7 ), commonly abbreviated as BDDMA, is a bifunctional methacrylate monomer used as a crosslinking agent across polymer and coating systems. By linking polymer chains at two reactive sites, it controls network density, hardness, and solvent resistance in cured materials. In UV- and peroxide-cured coatings, it increases crosslink density. This delivers harder, more chemically resistant films on wood, metal, and plastic substrates. Adhesive and sealant formulators incorporate it to tune cohesive strength and flexibility in structural systems. In plastics and polymer manufacturing, it acts as a crosslinker in suspension polymerization to produce beads and resins with controlled swelling behavior. This is a critical parameter for ion-exchange media. Personal care formulators use it to build film-forming polymer networks in nail gels and color cosmetics. Cure speed and film integrity are evaluated during qualification for these specific applications. BDDMA is supplied as a clear liquid, typically with an inhibitor added to prevent premature polymerization during storage and transport. Standard commercial grades are available at purities of 97% and above. Inhibitor type and concentration are specified on the product data sheet. Technical and specialty grades are offered to meet the requirements of coatings, adhesive, and personal care applications. Contact us for supply of 1,4-Butanediol dimethacrylate Request Quote

Other Names (Synonyms)

4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate | Butanediol dimethacrylate | BDDMA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point226.28 °C
Boiling Point110 °C @ Press: 3 Torr
Density1.011 g/cm³ @ Temp: 25 °C
Flash Point38 °F
ColorClear colorless to slightly yellow
FormLiquid
Water Solubility243mg/L at 20℃
Vapor Pressure430 mm Hg ( 25 °C)
Refractive Indexn 20/D 1.456(lit.)
Log P3.1 at 20℃

Safety & Handling

Warning
GHS07· IrritantGHS08· Health Hazard

Hazard Statements

H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H335May cause respiratory irritation
H361Suspected of damaging fertility or the unborn child
H401Toxic to aquatic life

Precautionary Statements

P203Obtain, consult and follow expert instructions for use.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P318IF exposed or concerned, get medical advice.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P317Get emergency medical help.
P317Get emergency medical help.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P364Take off contaminated clothing and wash it before reuse.
P233Store in a well-ventilated place. Keep container tightly closed.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29161400
UN Number2924
ADR Class3
Packing GroupII
Storage Class10 - Combustible liquids
WGK (Germany)2