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Cryolite

CAS Number
15096-52-3
EC Number
239-148-8
Chemical Formula
AlF6.3Na
Molecular Weight
209.941265 g/mol

Description

Cryolite (CAS 15096-52-3 ), also sold under the trade name Cryocide, is a synthetic sodium aluminum fluoride mineral used primarily as a flux and electrolyte medium in industrial processing. Commercially produced to replace the now-depleted natural mineral deposits, it is a critical input in aluminum smelting and select agrochemical and abrasive applications. In primary aluminum production, cryolite functions as the molten bath electrolyte in Hall-Héroult cells, dissolving alumina at high temperatures to enable electrochemical reduction into metal. This functionality makes it indispensable to smelter operations. Abrasive product manufacturers incorporate it as a filler and grinding aid in resin-bonded grinding wheels and coated abrasives. In these applications, it improves cut rate and extends wheel life. In the pulp and paper industry, it is used as an opacifying agent and filler to improve sheet brightness and printability. Historically applied as an insecticide under the Cryocide trade name, it remains a registered pesticide active ingredient in certain markets for control of chewing insects on crops. Cryolite is supplied as a fine white powder in bulk, supersacks, and bagged formats. Technical and metallurgical grades are the most common, with purity specifications typically aligned to industry standards. Pesticide-grade material is available in select markets where regulatory approvals are maintained. Our supply chain ensures consistent quality and reliable delivery for large-scale industrial requirements. Contact us for supply of Cryolite Request Quote

Other Names (Synonyms)

Trisodium hexafluoroaluminate | Cryolite (Na3(AlF6)) | Cryocide | Kryocide | Kryolith | ICE Spar | Cryolite (AlNa3F6) | Sodium aluminum fluoride

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point960-1027 °C
Boiling Pointdecomp
Density2.95 g/cm³
AppearanceSodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating)
synthetic product is an amorphous powder. Odorless
OdorOdorless
FormColorless, crystalline solid
Refractive Index1.338

Safety & Handling

Danger
GHS07· IrritantGHS08· Health HazardGHS09· Environment

Hazard Statements

H332Harmful if inhaled
H372Causes damage to organs through prolonged or repeated exposure
H411Toxic to aquatic life with long lasting effects
H412Harmful to aquatic life with long lasting effects

Precautionary Statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P391Collect spillage.
P501Dispose of contents/container in accordance with local regulations.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Trade & Regulatory

HS Code2826300000
UN Number3077
ADR Class9
Packing GroupIII
WGK (Germany)1