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Trisodium hexafluoroaluminate

CAS Number
13775-53-6
EC Number
237-410-6
Chemical Formula
AlF6.3Na
Molecular Weight
209.941265 g/mol

Description

Trisodium hexafluoroaluminate (CAS 13775-53-6 ), commercially known as cryolite, is a fluoride-based inorganic salt sourced both from natural mineral deposits and synthesized as a synthetic equivalent. In the aluminum smelting industry, it functions as the primary flux and electrolyte medium that enables the dissolution and electrochemical reduction of alumina into metallic aluminum. In aluminum production, cryolite forms the molten bath in Hall-Héroult electrolytic cells, directly determining process efficiency and metal purity. This makes it a critical procurement input for primary aluminum smelters. In agriculture, it is applied as a contact insecticide under the trade name Cryocide, targeting chewing insects such as grape phylloxera and citrus pests on crops where residue tolerances permit its use. Glass and enamel manufacturers incorporate it as a fluxing agent and opacifier to lower melting temperatures and improve surface finish in specialty coatings. It also serves as a catalyst component in certain systems. Synthetic cryolite is the dominant commercial form, available as a fine white powder or granules. It is supplied in technical and agricultural grades, with the agricultural specification subject to regional registration. Bulk supply is standard for metallurgical buyers, while smaller packaged quantities are available for agricultural and industrial use. The material is handled according to strict safety protocols for fluoride compounds. Contact us for supply of Trisodium hexafluoroaluminate Request Quote

Other Names (Synonyms)

CRYOLITE | Cryolite (Na3(AlF6)) | Cryocide | Kryocide | Kryolith | ICE Spar | Cryolite (AlNa3F6) | Sodium aluminum fluoride

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point1009 °C
Density1.941 g/cm³
AppearanceSodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating)
synthetic product is an amorphous powder. Odorless
ColorWhite
FormCrystals
Water SolubilitySparingly soluble in water(0.602 g/L at 20°C).
Refractive Index1.338

Safety & Handling

Danger
GHS07· IrritantGHS08· Health HazardGHS09· Environment

Hazard Statements

H332Harmful if inhaled
H372Causes damage to organs through prolonged or repeated exposure
H411Toxic to aquatic life with long lasting effects
H412Harmful to aquatic life with long lasting effects

Precautionary Statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P391Collect spillage.
P501Dispose of contents/container in accordance with local regulations.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Trade & Regulatory

UN Number3077
ADR Class9
Packing GroupIII
Storage Class6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects
WGK (Germany)1