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Phosphorus pentasulfide

CAS Number
1314-80-3
EC Number
215-242-4
Chemical Formula
P.S
Molecular Weight
444.6 g/mol

Description

Phosphorus pentasulfide (CAS 1314-80-3 ), also known as P4S10 and phosphorus persulfide, is a reactive inorganic compound used primarily as a chemical intermediate in the synthesis of organosulfur compounds. Its core industrial value lies in its ability to introduce both phosphorus and sulfur into organic molecules, making it a critical building block across agrochemical, lubricant additive, and mineral processing chemistries. In lubricant and metalworking fluid formulations, it serves as a precursor to zinc dialkyldithiophosphate (ZDDP) and related antiwear and extreme-pressure additives for high-performance applications. Agrochemical producers use it to manufacture dithiophosphate-based pesticides and insecticides, where controlled reactivity with alcohols and amines drives active ingredient synthesis for crop protection. In mining and flotation chemistry, dithiophosphate collectors derived from P4S10 improve selective mineral separation in sulfide ore processing, enhancing the efficiency of metal extraction operations. It also functions as a catalyst or reagent in specialty organic synthesis, including the production of pharmaceuticals and flame retardants, providing versatile chemical pathways for manufacturers. Phosphorus pentasulfide is supplied as a yellow-green powder or fused lump form, typically packaged under inert atmosphere due to its high moisture sensitivity and reactive nature. Technical and industrial grades are the standard commercial offering, with purity specifications commonly ranging from 98% to 100% P4S10 content. Bulk supply in drums or IBCs is standard for industrial buyers. Contact us for supply of Phosphorus pentasulfide Request Quote

Other Names (Synonyms)

sulfur phosphide | phosphorus persulfide | P4S10 | phosphorus sulfide | Tetraphosphorus decasulfide | Phosphoric sulfide | Diphosphorus pentasulfide | Thiophosphoric anhydride

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
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Physical Properties

Melting Point286-290 °C
Boiling Point513-515 °C
Density2.062 g/cm³
AppearancePhosphorus pentasulfide is a greenish-gray to yellow, crystalline solid with an odor of rotten eggs. The Odor Threshold is 0.005 ppm
ColorYellow to green
Odorrotten egg odor
FormPowder
Water Solubilityreacts
pH1 (10g/l, H2O, 20℃)

Safety & Handling

Danger
GHS02· FlammableGHS07· IrritantGHS09· EnvironmentGHS05· CorrosiveGHS06· ToxicGHS08· Health Hazard

Hazard Statements

H228Flammable solid
H260In contact with water releases flammable gases which may ignite spontaneously
H261In contact with water releases flammable gas
H301Toxic if swallowed
H302Harmful if swallowed
H311Toxic in contact with skin
H313May be harmful in contact with skin
H314Causes severe skin burns and eye damage
H315Causes skin irritation
H318Causes serious eye damage
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
H371May cause damage to organs
H400Very toxic to aquatic life H301+
H331Toxic if swallowed or if inhaled H302+
H332Harmful if swallowed or if inhaled

Precautionary Statements

P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P223Do not allow contact with water.
P240Ground and bond container and receiving equipment.
P241Use explosion-proof equipment.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P262Do not get in eyes, on skin, or on clothing.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P363Wash contaminated clothing before reuse.
P391Collect spillage.
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P232Handle and store contents under inert gas/… .
P265Wash … thoroughly after handling.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P317Get emergency medical help.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P364Take off immediately all contaminated clothing and wash it before reuse.
P364Take off contaminated clothing and wash it before reuse.
P378Use … for extinction.
P404Store in a dry place. Store in a closed container.
P233Store in a well-ventilated place. Keep container tightly closed.
P331Rinse mouth. Do NOT induce vomiting.
P334IF ON SKIN: Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P354IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code28139000
UN Number1340
ADR Class4.3
Packing GroupII
Storage Class4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK (Germany)3