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Triethyl phosphite

CAS Number
122-52-1
EC Number
204-552-5
Chemical Formula
C6H15O3P
Molecular Weight
166.16 g/mol

Description

Triethyl phosphite (CAS 122-52-1 ), commonly abbreviated as TEP, is a trialkyl phosphite ester used as a reactive intermediate and stabilizer across polymer, lubricant, and agrochemical manufacturing. Ethyl phosphite is a recognized alternative name in trade and procurement contexts. Its value lies in its ability to act as a ligand, antioxidant precursor, or catalyst component depending on the application. In polymer production, TEP functions as a stabilizer and processing aid, protecting polyolefins and engineering resins from oxidative degradation during high-temperature compounding processes. Lubricant and metalworking fluid formulators incorporate it as an antiwear additive precursor, where it reacts in situ to form protective phosphorus-containing films on metal surfaces. In agrochemical synthesis, TEP serves as a key building block for organophosphate active ingredients, including pesticides and herbicides produced via Michaelis–Arbuzov reactions. It also acts as a ligand precursor in transition metal catalyst systems used in polymerization and fine chemical processes. This versatility makes it essential for modern chemical synthesis. Triethyl phosphite is supplied as a clear, colorless liquid in standard drum and IBC packaging. Technical grade is the primary commercial specification, with purity levels typically ranging from 97% to 99%+. High-purity grades are available for catalyst and synthesis applications where trace impurities affect reaction selectivity. Proper handling is required to maintain the integrity of the chemical during storage. Contact us for supply of Triethyl phosphite Request Quote

Other Names (Synonyms)

Phosphorous acid, triethyl ester | Ethyl phosphite, (EtO)3P | Fosforyn trojetylowy | 6B2R04S55G | TRIS(ETHOXY)PHOSPHINE | Ethyl phosphite, Et3PO3 | TEP

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point-112 °C
Boiling Point157.9 °C
Density0.9629 g/cm³ @ Temp: 20 °C
Flash Point130 °F
AppearanceColorless liquid. Insoluble in water
soluble in alcohol and ether. Combustible.
Colorcolorless
Odorcharacteristic, obnoxious, phosphiteodor
Formliquid
Water Solubilityslightly soluble
Vapor Pressure<6 hPa (20 °C)
Refractive Indexn 20/D 1.413(lit.)

Safety & Handling

Warning
GHS02· FlammableGHS07· IrritantGHS08· Health Hazard

Hazard Statements

H226Flammable liquid and vapor
H302Harmful if swallowed
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H320Causes eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
H361Suspected of damaging fertility or the unborn child
H371May cause damage to organs
H402Harmful to aquatic life
H412Harmful to aquatic life with long lasting effects

Precautionary Statements

P203Obtain, consult and follow expert instructions for use.
P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233Keep container tightly closed.
P240Ground and bond container and receiving equipment.
P241Use explosion-proof equipment.
P242Use non-sparking tools.
P243Take action to prevent static discharges.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P317Get emergency medical help.
P318IF exposed or concerned, get medical advice.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P317Get emergency medical help.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P317Get emergency medical help.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P364Take off contaminated clothing and wash it before reuse.
P378Use … for extinction.
P233Store in a well-ventilated place. Keep container tightly closed.
P235Store in a well-ventilated place. Keep cool.
P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29209012
UN Number2323
ADR Class3
Packing GroupIII
Storage Class3 - Flammable liquids
WGK (Germany)1