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p-phenylenediamine

CAS Number
106-50-3
EC Number
203-404-7
Chemical Formula
C6H8N2
Molecular Weight
108.14 g/mol

Description

p-Phenylenediamine ( CAS 106-50-3 ), commonly abbreviated as PPD or p-Diaminobenzene, is an aromatic diamine used across polymer, textile, and cosmetic manufacturing. It functions primarily as a curing agent, dye intermediate, and antioxidant precursor in industrial formulations. In rubber and polymer processing, PPD derivatives serve as antiozonants and antidegradants, extending the service life of tires, belts, and industrial rubber goods. The textile and leather industries rely on PPD as a key intermediate in the synthesis of azo dyes and sulfur dyes. These applications enable deep, wash-resistant coloration on fiber substrates. In aramid fiber production, including high-performance materials like Kevlar, it acts as a monomer in polycondensation reactions. This contributes directly to tensile strength and flame resistance. Hair dye formulations in personal care use PPD as an oxidative colorant intermediate. In these applications, it reacts with hydrogen peroxide to produce permanent color. This chemical is essential for achieving long-lasting results in professional cosmetic products. p-Phenylenediamine is supplied as a crystalline solid, typically in flake or powder form. Technical grade is the standard offering for industrial polymer and dye applications. This ensures the material meets the necessary specifications for large-scale manufacturing. Material is commonly packaged in sealed, nitrogen-purged containers to maintain quality during storage and transit. Proper handling and storage are critical to prevent oxidation and ensure the chemical stability of the product upon arrival at your facility. Contact us for supply of p-phenylenediamine Request Quote

Other Names (Synonyms)

pPDA | paraphenylene-diamine | p-Diaminobenzene | benzene-1,4-diamine | 4-phenylenediamine | 4-Aminoaniline | 1,4-phenylenediamine | 1,4-diaminobenzene | PPD

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point145-147 °C
Boiling Point267 °C
Density1.1 g/cm³
Flash Point156 °C
Appearancep-Phenylenediamines are white to slightly red crystalline solids. They have been described as gray “light brown” which may result from exposure to air.
ColorWhite, gray, or purple to brown
FormPowder or Flakes
Water Solubility47 g/L (25 ºC)
Vapor Pressure1.08 mm Hg ( 100 °C)
Refractive Index1.6339 (estimate)
pH9 (50g/l, H2O, 20℃)
Log P-0.84 at 20℃

Safety & Handling

Danger
GHS06· ToxicGHS09· EnvironmentGHS07· IrritantGHS08· Health HazardGHS05· Corrosive

Hazard Statements

H301Toxic if swallowed
H311Toxic in contact with skin
H315Causes skin irritation
H317May cause an allergic skin reaction
H318Causes serious eye damage
H319Causes serious eye irritation
H320Causes eye irritation
H331Toxic if inhaled
H333May be harmful if inhaled
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H370Causes damage to organs
H372Causes damage to organs through prolonged or repeated exposure
H373May causes damage to organs through prolonged or repeated exposure
H400Very toxic to aquatic life
H410Very toxic to aquatic life with long lasting effects H301+H311+
H331Toxic if swallowed, in contact with skin or if inhaled

Precautionary Statements

P233Keep container tightly closed.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P262Do not get in eyes, on skin, or on clothing.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P284In case of inadequate ventilation wear respiratory protection.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P391Collect spillage.
P403Store in a well-ventilated place.
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P316Get emergency medical help immediately.
P352IF ON SKIN: Wash with plenty of water.
P317Get emergency medical help.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P317Get emergency medical help.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P316Get emergency medical help immediately.
P364Take off immediately all contaminated clothing and wash it before reuse.
P364Take off contaminated clothing and wash it before reuse.
P233Store in a well-ventilated place. Keep container tightly closed.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29215119
UN Number1673
ADR Class6.1
Packing GroupIII
Storage Class6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany)3