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Sodium hydrosulfide

CAS Number
16721-80-5
EC Number
240-778-0
Chemical Formula
HNaS
Molecular Weight
56.07 g/mol

Description

Sodium hydrosulfide ( CAS 16721-80-5 ), also known as sodium sulfhydrate and commonly abbreviated as NaHS, is an inorganic sulfide salt used across heavy industry as a reactive sulfur source and chemical intermediate. It functions primarily as a reducing agent, precipitant, and flotation reagent in processes where controlled sulfide chemistry is required. In mining and metals processing, NaHS is used as a selective flotation depressant. It acts as a metal sulfide precipitant to recover copper, zinc, and other non-ferrous metals from ore slurries. Pulp and paper manufacturers use it in kraft cooking liquor to improve pulping efficiency and delignification rates. Leather processors apply it as a depilatory agent to remove hair from hides during the beamhouse stage, a step critical to tannery throughput. In wastewater treatment, it precipitates heavy metals from industrial effluent streams. This process creates insoluble sulfides, supporting compliance with discharge limits. Sodium hydrosulfide is supplied as an aqueous solution, typically at concentrations around 45% NaHS, and in solid flake form. Technical grade is the standard commercial specification across most industrial applications. Solution grades are common for continuous-process industries due to handling and dosing convenience. Contact us for supply of Sodium hydrosulfide Request Quote

Other Names (Synonyms)

sodium sulfhydrate | sodium mercaptan | sodium hydrogen sulfide | sodium sulfide | Sodium bisulfide | Sodium sulfide (Na(SH)) | Sodium mercaptide | NaHS

Key Technical Features

  • High Purity Grade standard
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Physical Properties

Melting Point350 °C
Density1.79 g/cm³
Flash Point90°C
Appearancewhite crystals or powder with a very unpleasant smell
ColorOff-white
FormSolid
Water Solubility620 g/L (20 ºC)

Safety & Handling

Danger
GHS02· FlammableGHS05· CorrosiveGHS06· ToxicGHS09· EnvironmentGHS07· IrritantGHS08· Health Hazard

Hazard Statements

H226Flammable liquid and vapor
H251Self-heating; may catch fire
H290May be corrosive to metals
H301Toxic if swallowed
H312Harmful in contact with skin
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H335May cause respiratory irritation
H371May cause damage to organs
H400Very toxic to aquatic life

Precautionary Statements

P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233Keep container tightly closed.
P234Keep only in original packaging.
P235Keep cool.
P240Ground and bond container and receiving equipment.
P241Use explosion-proof equipment.
P242Use non-sparking tools.
P243Take action to prevent static discharges.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P363Wash contaminated clothing before reuse.
P390Absorb spillage to prevent material damage.
P391Collect spillage.
P405Store locked up.
P406Store in a corrosion-resistant/… container with a resistant inner liner.
P407Maintain air gap between stacks/pallets.
P410Protect from sunlight.
P413Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/…°F.
P420Store away from other materials.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P316Get emergency medical help immediately.
P352IF ON SKIN: Wash with plenty of water.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316Get emergency medical help immediately.
P364Take off contaminated clothing and wash it before reuse.
P378Use … for extinction.
P233Store in a well-ventilated place. Keep container tightly closed.
P235Store in a well-ventilated place. Keep cool.
P331Rinse mouth. Do NOT induce vomiting.
P354IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.