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o-Tolidine

CAS Number
119-93-7
EC Number
204-358-0
Chemical Formula
C14H16N2
Molecular Weight
212.29 g/mol

Description

o-Tolidine (CAS 119-93-7 ), also known commercially as 3,3'-dimethylbenzidine or DMB, is an aromatic diamine used as a chemical intermediate in the production of dyes, pigments, and curing agents. Its bifunctional amine structure makes it a reactive building block for synthesizing azo colorants and polyurea-based systems across several industrial sectors. In the dye and pigment industry, it is a key intermediate. This chemical is essential for manufacturing diazo-based yellow and orange pigments used in printing inks and packaging colorants. Textile and leather processors use DMB-derived dyes to achieve high-fastness coloration. These dyes are effective on both natural and synthetic substrates. In polymer and elastomer manufacturing, it functions as a curing agent for polyurethane and polyurea systems where controlled crosslink density is required. Specialty coatings formulators also source it as a precursor for producing performance pigments with strong lightfastness characteristics. This ensures long-lasting color stability in various industrial coating applications. The product is supplied as a solid, typically in flake or crystalline powder form. Technical grade is the standard commercial specification for industrial intermediate applications and large-scale manufacturing. It is available in bulk quantities suited to pigment manufacturers and polymer processors. Packaging options range from drums to bulk bags depending on specific volume requirements and logistical needs of the client. Contact us for supply of o-Tolidine Request Quote

Other Names (Synonyms)

3,3'-dimethylbenzidine | 4-(4-amino-3-methylphenyl)-2-methylaniline | DMB

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point129-131 °C
Boiling Point300 °C
Density1.234 g/cm³
Flash Point244 °C
Appearanceo-Tolidine is a white to reddish crystal or powder. Darkens on exposure to air. Often used in paste or wet cake form. Used as a basis for many dyes.
Colorlight brown
Formpowder (may contain lumps)
Water SolubilitySlightly soluble in water.
Refractive Indexn 20/D 1.341

Safety & Handling

Danger
GHS07· IrritantGHS08· Health HazardGHS09· Environment

Hazard Statements

H302Harmful if swallowed
H341Suspected of causing genetic defects
H350May cause cancer
H351Suspected of causing cancer
H372Causes damage to organs through prolonged or repeated exposure
H373May causes damage to organs through prolonged or repeated exposure
H401Toxic to aquatic life
H411Toxic to aquatic life with long lasting effects

Precautionary Statements

P203Obtain, consult and follow expert instructions for use.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P318IF exposed or concerned, get medical advice.
P319Get medical advice/attention if you feel unwell.
P330Rinse mouth.
P391Collect spillage.
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P317Get emergency medical help.

Trade & Regulatory

HS Code29215900
UN Number3082
ADR Class9
Packing GroupIII
Storage Class6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany)3