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4-hydroxybenzenesulfonic acid

CAS Number
98-67-9
EC Number
202-691-6
Chemical Formula
C6H6O4S
Molecular Weight
174.18 g/mol

Description

4-Hydroxybenzenesulfonic acid (CAS 98-67-9 ), also known as phenolsulfonic acid or sulfocarbolic acid, is an aromatic sulfonic acid used across industrial processing and formulation chemistry. It functions primarily as a pH buffer, UV stabilizer, and preservation agent in manufacturing workflows where precise acidity control and oxidative stability are required for the final product. In textile dyeing and leather tanning, it acts as a fixative and pH regulator, improving dye uptake and process consistency across batch production cycles and large scale industrial operations. Printing ink and packaging coating formulators incorporate it to stabilize pigment dispersions and extend shelf life against UV-induced degradation in various environmental conditions. In personal care formulations, it supports preservation systems and contributes to UV stabilization in products where phenolic-based protection is commercially preferred by manufacturers. Paper treatment processes use it as a buffering agent to control acidity during pulp processing and surface sizing, ensuring the structural integrity and quality of the finished paper goods. This chemical is supplied as an aqueous solution, with 65–70% concentration being the most commonly traded commercial form for global distribution and bulk industrial procurement. Technical grade is the standard offering for industrial applications in textiles, printing, and leather processing. Purity specifications may vary depending on specific application requirements. Contact us for supply of 4-hydroxybenzenesulfonic acid Request Quote

Other Names (Synonyms)

Sulfocarbolic acid | Phenolsulfonic acid | p-Sulfophenol | p-Hydroxybenzenesulfonic acid | Hydroxybenzene-4-sulfonic acid | 4-Sulfophenol | p-Phenolsulfonic acid | 4-Phenolsulfonic acid

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point52 °C
Boiling Point275.14°C (rough estimate)
Density1.337 g/cm³
Appearanceyellowish oily liquid
ColorWhite to Light yellow to Light red
FormLiquid
Water SolubilitySoluble in water.
Vapor Pressure69.8Pa at 20℃
Refractive Indexn 20/D 1.489
Log P0.41 at 25℃

Safety & Handling

Danger
GHS05· CorrosiveGHS07· Irritant

Hazard Statements

H290May be corrosive to metals
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H335May cause respiratory irritation

Precautionary Statements

P234Keep only in original packaging.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P363Wash contaminated clothing before reuse.
P390Absorb spillage to prevent material damage.
P405Store locked up.
P406Store in a corrosion-resistant/… container with a resistant inner liner.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P317Get emergency medical help.
P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P233Store in a well-ventilated place. Keep container tightly closed.
P331Rinse mouth. Do NOT induce vomiting.
P354IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29089990
UN Number2586
ADR Class8
Packing GroupIII
Storage Class8A - Combustible corrosive hazardous materials