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Calcium nitrite

CAS Number
13780-06-8
EC Number
237-424-2
Chemical Formula
Ca.2HNO2
Molecular Weight
132.09 g/mol

Description

Calcium nitrite ( CAS 13780-06-8 ) is an inorganic calcium salt used industrially as a corrosion inhibitor and accelerating admixture in construction and infrastructure applications. It is occasionally referenced under the Caswell No. 147 designation in regulatory contexts. Its primary commercial value lies in protecting embedded steel reinforcement from chloride-induced corrosion while simultaneously accelerating early concrete strength development. In reinforced concrete structures, it is dosed as an admixture to extend service life. Bridges, parking decks, marine infrastructure, and below-grade foundations utilize this chemical in chloride-rich environments. Precast concrete producers use it to shorten demolding cycles by accelerating cement hydration at lower temperatures. In oil and gas well cementing, it functions as a set accelerator under cold downhole conditions. The mining sector uses the compound in grouting operations and in corrosion protection treatments for steel ground support elements. Calcium nitrite is supplied primarily as an aqueous solution, with 30% and 35% concentrations being the most commercially standard for concrete admixture use. Solid forms, including powder and granules, are available for specific applications. These solid formats are preferred where liquid handling or freight costs are a constraint. Technical grade is the predominant specification across construction and mining end uses, ensuring reliable performance in heavy industrial settings. Contact us for supply of Calcium nitrite Request Quote

Other Names (Synonyms)

calcium dinitrite | Nitrous acid, calcium salt | Caswell No. 147 | Nitrous acid calcium salt (2:1) | EPA Pesticide Chemical Code 076202 | F538343O0T | Calcium nitrite (Ca(NO2)2)

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

Physical Properties

Melting Point390 °C
Density2.23
Flash Point110 °C
Colorwhite-yellow hexagonal, hexane crystals, crystalline
hygroscopic
OdorOdorless
Formwhite-yellow hexagonal crystals
Water Solubilityslightly soluble alcohol [MER06]
g/100g solution H2O38.3 (0°C), 43.0 (18.5°C), 71.2 (91°C)
solid phase Ca(NO2)2 · 4H2O (0°C, 18.5°C), Ca(NO2)2 ·2H2O (91°C) [KRU93]
Refractive Indexn 20/D 1.3946
Log P-2.52 at 20℃

Safety & Handling

Danger
GHS03· OxidizerGHS05· CorrosiveGHS06· ToxicGHS07· IrritantGHS09· EnvironmentGHS08· Health Hazard

Hazard Statements

H272May intensify fire; oxidizer
H301Toxic if swallowed
H302Harmful if swallowed
H318Causes serious eye damage
H319Causes serious eye irritation
H370Causes damage to organs
H372Causes damage to organs through prolonged or repeated exposure
H373May causes damage to organs through prolonged or repeated exposure
H400Very toxic to aquatic life
H410Very toxic to aquatic life with long lasting effects

Precautionary Statements

P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P220Keep away from clothing and other combustible materials.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P317Get emergency medical help.
P319Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P391Collect spillage.
P405Store locked up.
P501Dispose of contents/container in accordance with local regulations.
P265Wash … thoroughly after handling.
P316Get emergency medical help immediately.
P317Get emergency medical help.
P316Get emergency medical help immediately.
P317If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P378Use … for extinction.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

Storage Class10 - Combustible liquids
WGK (Germany)3